Best Bond...well, for me it's a tie between Sean Connery and Daniel Craig. I love them both in the role for different reasons. If I really had to choose, it would be Sean Connery although I really think Daniel Craig's Bond is closest to how Ian Fleming intended him to be. Although to be honest, the only one I'd say I disliked at all was Roger Moore and even then I don't actually dislike him in the role - I just wasn't keen on the movies he starred in.
As for best movie - again it's a tie. I love From Russia With Love, but at the same time I love Casino Royale. I think I'd have to choose From Russia With Love purely because it's more classic-Bond. Although I should also mention that my very close runner up for my favourite movie was On Her Majesty's Secret Service.