Is it possible to copy -NOT SYNC - music and videos onto iphone or itouch?

When you sync the songs, you copy them to the itouch, so you could delete the songs from your HDD once you copied them once, but I wouldn't recomend that as you can't copy songs from your iphone to your HDD and if anything happens to your iphone or itouch, you can't restore it without a second copy of the songs.
 
The term "sync" replaces "copy" when it comes to devices like that. If this works i be lucky connect your device and go to my computer and click on your device. To show its actual files click on tools> folder options> view tab then select "show hidden files/folders" that should do it
 
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