How can i count pot odds Pre-Flop in Texas Hold Em'?

if it's head's up and there's 10 dollars in the pot and i have AQ and i think i have the better hand and i think he knows he has a worse hand, how much should i bet to try to take the pot? like statistically so he won't mathematically be making a good choice by calling.

(for example if there's $10 in the pot and i bet $5 and he has a 33% chance of winning, should he call the $5?)
 
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