I've done the unthinkable and found a couple for each category. :lol: In the Random and Cheesiest categories, I put couples I am NOT a fan of. The rest of the couples I have been a fan of or still am.
Prettiest Couple: Sawyer and Kate, Lost
Angsty-est Couple: Kyle and Jessi, Kyle XY
Funniest Couple: Sheldon and Penny, The Big Bang Theory
Cheesiest Couple: Nathan and Haley, One Tree Hill
Most Romantic Couple: Sonny and Brenda, General Hospital
Couple with the Best First Kiss: Bay and Emmett, Switched at Birth
Couple with the Best Wedding: Seth and Summer, The O.C.
Couple that Everyone Seems to Like: Tony and Ziva, NCIS
Couple with the Most 'Unresolved Sexual Tension: Elliot and Olivia, Law & Order: Special Victims Unit
Couple with the Best FrienRABhip: Abby and Gibbs, NCIS
Official Top Couple of All-Time: Simon and Katie, As The World Turns
Official Top Couple Currently: Jane and Lisbon, The Mentalist
Most Intriguing Couple: Damon and Elena, The Vampire Diaries
Couple with The Best Bickering: Matt and Maxie, General Hospital
Couple with the Best Chemistry: Jason and Elizabeth, General Hospital
Couple with the Best First Meeting: Aria and Ezra, Pretty Little Liars
Couple That Would Make The Cutest Kid: Ross and Rachel, FrienRAB (Oh, wait they already did make a BEAUTIFUL baby.)
Couple with the Best Profession of Love: Angela and Hodgins, Bones
Couple That Took The Longest To Hook Up: Luke and Lorelai, Gilmore Girls
Couple You Want To Hook Up: Peter and Claire, Heroes
Most underrated couple: Creegan and Susan, Touching Evil (USA network's version.)
Most adorable couple: Rory and Jess, Gilmore Girls
Couple with the best reunion(s): Charlie and Claire, Lost
Couple that neeRAB to get back together: Mark and Lexie, Grey's Anatomy
Most passionate couple: Denny and Izzie, Grey's Anatomy
Most innocent couple: Andy and Josh, Kyle XY
Couple with the best love scene: Jax and Skye, General Hospital
Couple who has the best eye sex: House and Cameron, House M.D.
Couple you want to end up happily ever after: Castle and Beckett, Castle
The last couple you fell for: Daphne and Wilke, Switched at Birth
Most Unlikely couple: Goren and Eames, Law & Order: Criminal Intent
Couple that Should Have Ended up Together: Jake and Peyton, One Tree Hill
First Couple You Ever Loved: Lucy and Carter, ER
Favorite Movie Couple: Ron and Hermione, Harry Potter Series
Favorite Book Couple: Darcy and Ethan, Something Borrowed Series by Emily Giffin
Couple with the Best Kisses: Ryan and Taylor, The O.C.
Most Heartbreaking Couple: Jenn and Jack, Dawson's Creek
Most Random Couple: Ben and Adrian, The Secret Life of the American Teenager
Best Love Triangle: Lori and Declan and Hillary, Kyle XY (Loved Declan and Lori the most, but I didn't at all mind him with Hillary. Too bad it was never resolved.)
Most Disappointing Couple: Alex and Ava, Grey's Anatomy
Most Natural Couple: Melissa and Joey, Melissa & Joey
Most Realistic Couple: Abby and Carter, ER
Couple Most In Love: Phoebe and Cole, Charmed
Couple With the Best Ending: Pacey and Joey, Dawson's Creek
Most "Epic" Couple: Bones and Booth, Bones
Couple with the best written love story (doesn't necessarily have to be your OTP): Piper and Leo, Charmed
Couple that you hated/thought you would hate but ended up loving: Buffy and Spike, Buffy the Vampire Slayer
Couple that you love but don't care that they aren't endgame/don't need them to be endgame: Lauren and Carter, Make It or Break It
Favorite married couple: Frank and Denise, Army Wives
Best dressed couple: Dan and Serena, Gossip Girl
Couple that has the most baggage/issues: Jack and Sam, Without A Trace
Couple with the best erabraces/hugs: Angel and Cordelia, Angel
Couple with the best marriage proposal: David and Donna, Beverly Hills 90210
Couple that shattered your heart to a million pieces but will never stop loving: Brooke and Lucas, One Tree Hill
Couple that didn't get the ending they deserved: Justin and Rebeca, Brothers & Sisters
Best couple on current TV: Ricky and Amy, The Secret Life of the American Teenager