That's not entirely true. Unless I misunderstand what you meant... The battery usage information always total 100%, whether you've used 1%, 10% or 99% of your battery. The percentages for each item listed are the percentages of the total used power since the phone was unplugged.
What you want to do is leave the phone as long as possible (either until the end of the day, or until it starts complaining that the battery is low), and then look at the statistics. If you're not doing much else on your phone (i.e. no calls, no WiFi, display off) then the next biggest users of power tend to be Cell standby, Android system, and Phone idle. Between those three they could easily make up 99% of your battery use.