To drain the water (coolant) from a car radiator, you use a plug at the BOTTOM of the radiator. It will not drain from the whole system, but it will drain from the radiator itself.
The cap should be on top of the radiator, BUT some cars do not have it there. It it's not there, use the cap on top of the plastic reservoir (it's usually inside the engine compartment, maybe above the wheel somewhere. It looks like a gallon size tank connected to the radiator by a hose.)