Where is the best new england backpacking outside of the appalachian trail?

Looking for about one week's worth of not-too-intense backpacking (this will be 4 out of 6 of my party's second time backpacking) within about 150 miles of Boston. Following a mountain range is great, following a river is even better, as long as there are trees to set up our hammocks. Preferably fires should be allowed at least at campsites. We are looking especially at maine. Having enjoyed the AT many times I'm looking for something else this time. Suggestions appreciated.

P.S. Or can you suggest a location for a multi-day canoe trip? We are looking at that as well.
 
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