If I join the Army National Guard and want to deploy, how easy would it be for me to...

...get a deployment? I'm joining the national guard so I can finish up my college degree, but I still would like to deploy and do my part. Would I be able to pick up a deployment after I finish college? How hard or easy would it be? I wouldnt have an issue with relocating.

To clarify, I will be going into the guard as an 11 series MOS. I'm wondering if a unit is being mobilized if I can volunteer to mobilize with a different unit in a different state if they have an opening, would they even have an opening of they're mobilizing, or could I trade orders with someone who is mobilizing etc.
 
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