How to choose color for shading cartoon characters?

Kim

New member
Hi, I'm NOT asking about the skills in photoshop or any other digital animation programs.
I've been painting cartoon characters with acrylic colors and also been failing to shade.
I think the main reason is because I just add black to original colors.
It seems there must be more than that.
How to choose appropriate colors to shade?
Is there a color chart for that?
Thanks in advance.
 
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