I burned the fuck out of my toes several weeks ago. Some mashed pototoes (long story) straight out of the microwave fell right in between two of my toes and I dont know if you've ever had scalding hot mashed potatoes between your toes or not but you dont want to stick your fingers through your toes either because it's so hot. I had to find a dish towel and scoop it out.
Either way, I had blisters there for a week, and I limped for about 3 weeks until I could walk properly in shoes again. It was quite rough. Especially the first 3 hours... but pretty much teh entire area between those two toes was nothing but blistered burn.
But at least I didnt burn my face.