There wouldn't be any strict order to purchasing the new parts, except I would have the PCV+AT ready when you do your cam swap, as there will be a big change in tuning after the cams are installed. Since you have an '07 I could give you my map files for the 255's, which will be close since the only difference is the pipes (I have Jackpots) and would be a good place to start. With the values close AT will trim much more quickly toward an optimum tune.
If you want to install the PCV-AT first and run it with your stock cams I have maps for that setup too.
Either way is fine, but I think I would just go ahead and buy the entire PCV-AT package and familiarize yourself with it early.
That's easy to set-up and any on-off switch will do. With AT you can switch between open-loop (base map) and closed-loop (auto-tune), so at first I ran the bike with richer target AFR's, then "Accept Trims" to write a new base map, and finally change the target AFR's in the cruise range only to leaner values for gas mileage. That will make AT trim leaner for better mileage (most riding) and run richer (base map only) when you flip the switch. It works great.